Abstract
Studies of the combustion of
n
-hexane with special reference to the
O
-heterocyclic products formed show that these compounds are present in the largest quantities under cool flame conditions and that their concentration decreases sharply at the ignition boundary.
O
-heterocyclic compounds appear to be the main products of the intramolecular rearrangement of hexylperoxy radicals and their structure shows that they are derived predominantly from the 2-hexylperoxy radical. The amounts of the different
O
-heterocycles produced can, on the basis of reasonable assumptions, provide information regarding the relative susceptibility to intramolecular hydrogen abstraction of the 3-, 4- and 5-positions in the 2-hexylperoxy radical.
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