Abstract
It is known that the electrostatic long-range forces between two molecules are 'locally additive' in the sense that the first-order interaction energy between molecules bearing charges or permanent multipole moments may be written as a double integral over pairs of points, one in each molecule. In this paper we examine the second-order interaction energy, which comprises polarization and dispersion terms, and find that the corresponding forces are locally additive or not according as the electron correlation within each molecule does or does not die away rapidly with distance.
Reference12 articles.
1. C oulson C. A. & D avies P . L .
2. Phys. 1952 Trans;Faraday Soc.,1920
3. Phys;Ik;Z .,1922
4. Z . phys;Chem. B,1930
5. Proc. Roy;Soc. A,1956
Cited by
38 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献