The spin-orbit interaction in d 3 complexes

Author:

Abstract

The spin-orbit interaction in d n complexes is discussed using the tensor operator methods of Tanabe & Kamimura, and some of their tables of transformation coefficients are extended. The complete spin-orbit matrices for the d 3 , d 7 configurations are given in a strong cubic field scheme. Using these matrices and probable values of parameters, we have calculated energy levels for trivalent chromium in magnesium oxide and for potassium hexachloromolybdate and iridium hexafluoride.

Publisher

The Royal Society

Subject

Pharmacology (medical)

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