Abstract
The microwave rotational spectrum of the hydrogen-bonded, linear heterodimer HCN • • • HF has been identified and a number of spectroscopic constants have been measured in a detailed analysis. The spectroscopic constants have been used in a variety of ways in order to evaluate parameters characterizing the potential energy function of the isolated dimer. An investigation of the Stark effect of two rotational transitions of HCN • • • HF has led to an accurate value of the electric dipole moment of the dimer and hence to the enhancement on dimer formation.
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