Push-pull systems based on 2,4,6-triaryl pyrimidines. 2,4-diaryl-6- and 2-aryl-4,6-bis{4-[(<i>E</i>)-2-arylvinyl]phenyl}pyrimidines

Author:

Harutyunyan A. A12,Safaryan M. S2,Dilanyan S. V2,Panosyan H. A2,Danagulyan G. G12

Affiliation:

1. Russian-Armenian (Slavonic) University

2. Scientific Technological Center of Organic and Pharmaceutical Chemistry (STCOPHCH)

Abstract

Previously undescribed 2,4,6-triarylpyrimidines were synthesized by condensation of benzamidine and 4-(methyl-, 4-butoxy)benzamidine hydrochlorides with ( E )-1,3-diaryl-2-propen-1-ones in alcohol in the presence of KOH. The latter were reacted with ( E )- N -(2-chlorophenyl)-1-arylmethanimines in the KOH/LiH/DMF system to give 2,4-diaryl-6- and 2-aryl-4,6-bis{4-[( E )-2-arylvinyl]phenyl}-pyrimidines.

Publisher

The Russian Academy of Sciences

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