Synthesis of tetrazinyl biradicals containing a <i>p</i>-phenylene fragment

Author:

Kostryukov S. G1,Burtasov A. A1,Dolganov A. V1,Kozlov A. Sh.1,Konushkin I. A1,Malov N. A1,Krasnov D. A1,Asfandeev A. Yu.1

Affiliation:

1. National Research Ogarev Mordovia State University

Abstract

3,3′-(1,4-Phenylene)bis[1-(4-R-phenyl)-5-phenyl-5,6-dihydro-1,2,4,5-tetrazinium] perchlorates were transformed into stable tetrazinyl biradicals by the action of D-glucose in slightly alkaline medium (NH4OH) in the presence of air oxygen. The tetrazinyl biradicals were isolated in individual state and characterized by cyclic voltammetry, elemental analysis, IR, UV, EPR spectroscopy methods.

Publisher

The Russian Academy of Sciences

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5. Advances in verdazyl chemistry

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