Comparison of the Hydrocarbon Distribution in Thermolysis Products of Asphaltenes, Resins, and Acids Isolated from Weakly Transformed Crude Oil from the Anastasievsko-Troitskoe Oil Field (Horizon IV)

Author:

Gordadze G. N.1,Vasil'eva A. V.1,Vylekzhanina D. S.1,Gadzhiev G. A.1,Stokolos O. A.1

Affiliation:

1. Gubkin Russian State University of Oil and Gas (National Research University)

Abstract

Regular trends in the distribution of hydrocarbon biomarkers (n-alkanes, isoprenanes, steranes, and terpanes) and hydrocarbons of the adamantane series in low-maturity crude oil from the Anastasievsko-Troitskoe oil field (horizon IV) and in products formed by thermolysis of asphaltenes, resins, and acids from this oil were studied by gas chromatography–mass spectrometry. Thermolysis of high-molecular-mass oil precursors yields the same hydrocarbons (HCs) as those present in the initial oil, and also protoadamantanes (precursors of adamantanes). HCs of the adamantane series are not formed, and their presence in this crude oil is due to their supply from other oil source strata. The experiments show that the n-alkanes present in the initial oil in small amounts are released under more severe conditions.

Publisher

The Russian Academy of Sciences

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