Palladium Complexes of Pyrimidine-2-thiones: Synthesis, Structures, and Properties-Reference-Cited by-同舟云学术

Palladium Complexes of Pyrimidine-2-thiones: Synthesis, Structures, and Properties

Published:2024-08-01 Issue:1 Volume:50 Page:53-61
ISSN:0132-344X
Container-title:Координационная химия
language:
Short-container-title:Koordinacionnaâ himiâ

Author:

Kuzovlev A. S.¹²,Gordeeva N. A.³,Pastukhova Zh. Yu.³,Chernyshev V. V.¹⁴,Buzanov G. A.⁵,Dunaev S. F.¹,Bruk L. G.³

Affiliation:

1. Moscow State University

2. Tyumen State University

3. Russian Technological University (MIREA)

4. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

5. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Abstract

Complexes [PdL2Cl2] (I) and [PdL2Вr2] (II) (L is 5-acetyl-6-methyl-4-(3-nitrophenyl)-1,2,3,4-tetrahydropyrimidine-2-thione) are synthesized and characterized by spectral methods (1Н, 13С NMR and IR spectroscopy). The crystal structure of complex I is determined (CIF file ССDС no. 2233053) in which the palladium atom is coordinated by two halide ions and two sulfur atoms of two ligands L in a distorted square planar geometry. The catalytic activity of the synthesized palladium(II) complexes in the model epoxidation of allyl alcohol is estimated in comparison with the catalytic activity of the corresponding palladium halides and titanium-containing zeolite TS-1.

Publisher

The Russian Academy of Sciences

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