SOLVENT EFFECTS ON THE ELECTRONIC AND IONIC CONDUCTIVITY IN POLYMERIC NICKEL(II) COMPLEX OF N,N′ BIS(3 METHOXYSALICYLIDENE)ETHYLENEDIAMINE-Reference-Cited by-同舟云学术

SOLVENT EFFECTS ON THE ELECTRONIC AND IONIC CONDUCTIVITY IN POLYMERIC NICKEL(II) COMPLEX OF N,N′ BIS(3 METHOXYSALICYLIDENE)ETHYLENEDIAMINE

Published:2023-11-01 Issue:11 Volume:59 Page:659-673
ISSN:0424-8570
Container-title:Электрохимия
language:
Short-container-title:Èlektrohimiâ

Author:

Smirnova E. A.¹,Chepurnaya I. A.¹

Affiliation:

1. Ioffe Physical Technical Institute of the Russian Academy of Sciences (Ioffe Institute)

Abstract

The electrochemical oxidation-reduction of polymeric nickel(II) complex of N,N′-bis(3-methoxysalicylidene)ethylenediamine was investigated in acetonitrile and 1,2-dichloroethane-based solutions by a combination of in situ conductance measurements, quartz crystal microbalance, and cyclic voltammetry. The type of electrolyte solution is shown to have a pronounced effect on the variations in the electrical conductance and ion and solvent transfer at the polymer/solution interface when the polymer is electrochemically switched between various oxidation states.

Publisher

The Russian Academy of Sciences

Reference50 articles.

1. Clarke, R.M., Herasymchuk, K., and Storr, T., Electronic structure elucidation in oxidized metal–salen complexes, Coord. Chem. Rev., 2017, vol. 352, p. 67.

2. Thomas, F., Ligand-centred oxidative chemistry in sterically hindered salen complexes: an interesting case with nickel, Dalton Trans., 2016, vol. 45 (27), p. 10866.

3. Zhang, J., Xu, L., and Wong, W.Y., Energy materials based on metal Schiff base complexes, Coord. Chem. Rev., 2018, vol. 355, p. 180.

4. Freire, C., Nunes, M., Pereira, C., Fernandes, D.M., Peixoto, A.F., and Rocha, M., Metallo(salen) complexes as versatile building blocks for the fabrication of molecular materials and devices with tuned properties, Coord. Chem. Rev., 2019, vol. 394, p. 104.

5. Chepurnaya, I.A., Karushev, M.P., Alekseeva, E.V., Lukyanov, D.A., and Levin, O.V., Redox-conducting polymers based on metal-salen complexes for energy storage applications, Pure Appl. Chem., 2020, vol. 92, no. 8, p. 1239.