Improvement in Wide-Gap A-SI:H For High-Efficiency Solar Cells

Author:

Tsuge Sadaji,Hishikawa Yoshihiro,Okamoto Shingo,Sasaki Manabu,Tsuda Shinya,Nakano Shoichi,Kuwano Yukinori

Abstract

ABSTRACTA hydrogen-plasma treatment has been used for the first time to fabricate wide-gap, high-quality a-Si:H films. The hydrogen content (CH) of a-Si:H films substantially increases by the hydrogen-plasma treatment after deposition, without deteriorating the opto-electric properties of the films. The photoconductivity (σph) of ≥ 10-5 ο-1 cm-1, photosensitivity ( σ ph/σ d) of > 106 and SiH2/SiH of <0.2 are achieved for a film with CH of ∼25 atomic >%. The optical gap of the film is > 1.70 eV by the (α h ν )1/3 plot, and is >2 eV by the Tauc's plot. The open circuit voltage of a-Si solar cells exceeds 1 V conserving the fill factor of > 0.7 when the wide-gap a∼Si:H films are used as the i-layer, which proves the wide band gap and low defect density.

Publisher

Springer Science and Business Media LLC

Subject

General Engineering

Reference8 articles.

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3. Interference-Free Determination of the Optical Absorption Coefficient and the Optical Gap of Amorphous Silicon Thin Films

4. [3] Nishiwaki H. , Ohnishi M. , Haku H. , Dohjoh H. , Sayama K. , Hishikawa Y. , Nakashima Y. , Wakizaka K. , Tsuda S. , Nakano S. , Kishi Y. and Kuwano Y. in Proceedings of the 6th International Photovoltaic Science and Engineering Conference, India, 469 (1992)

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