Author:
Jaumier Pascale,Jousseaume Bernard,Riague Hocine,Toupance Thierry,Lahcini Mohamed
Abstract
ABSTRACTFunctional trialkynylorganotins were obtained by alkynylation of the
corresponding organotin trichlorides. When functional organotin trichlorides
were not stable, a selective monoalkynylation of tetraalkynyltins by
Grignard reagents was used. It was the first example of selective
monoalkylation reactions of symmetrically tetrasubstituted tin compounds.
Then, reactions of the functional trialkynylorganotins with alcohols, water
and carboxylic acids afforded respectively the corresponding functional
monoorganotin alkoxides and oxides, and monoorgano-oxotins carboxylates.
Publisher
Springer Science and Business Media LLC
Cited by
1 articles.
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