Stability Studies of Hydrogenated Amorphous Silicon Alloy Solar Cells Prepared with Hydrogen Dilution

Abstract

ABSTRACTWe have fabricated hydrogenated amorphous silicon alloy solar cells using hydrogen dilutions at 175 °C and 300 °C, and obtained improved photovoltaic characteristics in both the initial and degraded states for the highly diluted cells; both the fill factor and the open-circuit voltage exhibit higher values before and after light soaking. Infrared analyses reveal that for a given deposition temperature the amount of bonded hydrogen has similar concentrations between the high and low hydrogen diluted samples. Optical Modelling shows a 20 MeV difference in their optical bandgap. Defect densities obtained from constant photocurrent measurements give similar values for a given deposition temperature both before and after light soaking, inconsistent with solar cell performance.