Microstructure and Chemistry of an Aluminophosphate Glass Waste Form under Electron Beam Irradiation

Abstract

ABSTRACTAn alkali-containing (mainly sodium) aluminophosphate glass waste form was studied by analytical electron microscopy. Bright-field imaging showed that small bubbles formed under the electron irradiation even at a low electron dose (8×1022e/m2). These bubbles grew with the increase of the electron dose and were finally released at the surface of the sample. At the same time alkali elements were also lost under irradiation. At an electron dose of about 2.2×1026e/m2 (6.6×1011Gy), all the bubbles were released and no bubbles were formed with further irradiation. The glass was finally transformed to a pure aluminophosphate glass. Further irradiation resulted in the phase separation between the Al-rich and the P-rich phases. The electron irradiation damage effects on the aluminophosphate glass are compared to those observed in iron phosphate glasses.