BENFEP Spheres: New Porous Adsorbent Material for Arsenic Removal from Natural Waters

Author:

Acarapi-Cartes Jorge1ORCID,Cornejo-Ponce Lorena23ORCID

Affiliation:

1. Programa de Doctorado en Química, Departamento de Ciencias Químicas y Farmacéuticas, Facultad de Ciencias de la Salud, Universidad Arturo Prat, Avenida Arturo Prat 2120, Iquique 1100000, Chile

2. Laboratorio de Investigaciones Medioambientales de Zonas Áridas (LIMZA), Facultad de Ingeniería, Universidad de Tarapacá, Avenida General Velásquez 1775, Arica 1000007, Chile

3. Departamento de Ingeniería Mecánica, Facultad de Ingeniería, Universidad de Tarapacá, 18 Septiembre 2222, Arica 1010069, Chile

Abstract

In the present work, the adsorption of arsenic (V) on a new porous material (named BENFEP), was studied for the first time. The parameters pH, adsorbent dosage, initial concentration and contact time were evaluated on the adsorption performance in a batch system. The results show that maximum arsenic removal is achieved at pH 7.0–7.5 with 1.5 g/L adsorbent. The observed data were found to follow the Langmuir adsorption isotherm between pH values of 5 and 9, indicating that the adsorbent had mainly homogeneous sites on its surface. The experimental data obtained from the thermodynamic study showed that the reaction was viable, spontaneous and exothermic. No significant deterioration in water quality was observed after the adsorption process, a characteristic that is fundamental for its application in small-scale water treatment systems, particularly in isolated rural areas.

Funder

Project Fondecyt Regular

Agencia Nacional de Investigación y Desarrollo

Ministerio de Ciencia

Tecnología, Conocimiento e Innovación

Gobierno de Chile

Publisher

MDPI AG

Subject

Water Science and Technology,Aquatic Science,Geography, Planning and Development,Biochemistry

Reference79 articles.

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2. Heavy metals in drinking water: Occurrences, implications, and future needs in developing countries;Chowdhury;Sci. Total Environ.,2016

3. National Academy of Sciences (NAS) (2001). Arsenic in Drinking Water, National Academy of Sciences.

4. Negative pH, efflorescent mineralogy, and consequences for environmental restoration at the Iron Mountain Superfund site California;Nordstrom;Proc. Natl. Acad. Sci. USA,1999

5. (2023, June 12). Addendum to the Toxicological Profile for Arsenic, Available online: https://www.atsdr.cdc.gov/substances/toxsubstance.asp?toxid=3.

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