A Formulation Model to Compute the Life Cycle Environmental Impact of NiZn Batteries from Cradle to Grave

Abstract

This paper presents a comprehensive and systematic analysis of the environmental impacts (EI) produced by novel nickel-zinc battery (RNZB) technology, which is a promising alternative for energy storage applications. The paper develops mathematical models for estimating the life cycle environmental impacts of RNZB from cradle to grave, based on an extensive literature review and the ISO standards for life cycle costing and life cycle analysis. The paper uses the ReCiPe 2016 method of life cycle analysis (LCA) to calculate the EI of RNZB in terms of eighteen Midpoint impact categories and three Endpoint impact categories: damage to human health, damage to ecosystem diversity, and damage to resource availability. The paper also compares the EI of RNZB with those of other battery technologies, such as lead-acid and lithium-ion LFP and NMC. The paper applies the models and compares results with those provided by the software openLCA (version 1.11.0), showing its reliability and concluding that NiZn batteries contribute approximately 14 MJ for CED and 0.82 kg CO2 eq. for global warming per kWh of released energy, placing them between lithium-ion and lead-acid batteries. This study suggests that NiZn battery technology could benefit from using more renewable energy in end-use applications and adopting green recovery technology to reduce environmental impact. Further developments can use these models as objective functions for heuristic optimisation of the EI in the life cycle of RNZB.