Laser-Assisted Preparation of TiO2/Carbon/Ag Nanocomposite for Degradation of Organic Pollutants

Abstract

The ever-increasing expansion of chemical industries produces a variety of common pollutants, including colors, which become a global and environmental problem. Using a nanocatalyst is one of the effective ways to reduce these organic contaminants. With this in mind, a straightforward and effective method for the production of a novel nanocatalyst based on lignin-derived carbon, titanium dioxide nanoparticles, and Ag particles (TiO2/C/Ag) is described. The preparation of carbon and Ag particles (in sub-micro and nano size) was carried out by laser ablation in air. The nanocomposite was synthesized using a facile magnetic stirrer of TiO2, C, and Ag. According to characterization methods, a carbon nanostructure was successfully synthesized through the laser irradiation of lignin. According to scanning electron microscope images, spherical Ag particles were agglomerated over the nanocomposite. The catalytic activities of the TiO2/C/Ag nanocomposite were tested for the decolorization of methylene blue (MB) and Congo red (CR), employing NaBH4 in a water-based solution at 25 °C. After adding fresh NaBH4 to the mixture of nanocomposite and dyes, both UV absorption peaks of MB and CR completely disappeared after 10 s and 4 min, respectively. The catalytic activity of the TiO2/C/Ag nanocomposite was also examined for the reduction of 4-nitrophenol (4-NP) using a NaBH4 reducing agent, suggesting the complete reduction of 4-NP to 4-aminophenol (4-AP) after 2.30 min. This shows excellent catalytic behavior of the prepared nanocomposite in the reduction of organic pollutants.