Trade-Off between Degradation Efficiency and Recyclability: Zeolite-Enhanced Ni3−xCoxS4 Catalyst for Photocatalytic Degradation of Methylene Blue

Author:

Lagunay Rachel Anne E.12,Adalim Ritche Roi B.2,Tleubekova Aruzhan3,Suleimenova Diana45,Fernandez Marvin Jose F.2ORCID,O’Reilly Robert J.6ORCID,Balanay Mannix P.1ORCID

Affiliation:

1. Department of Chemistry, Nazarbayev University, Astana 010000, Kazakhstan

2. Department of Chemistry, Mindanao State University-Iligan Institute of Technology, Iligan City 9200, Philippines

3. Department of Biology, Nazarbayev University, Astana 010000, Kazakhstan

4. National Laboratory Astana, Nazarbayev University, 53 Kabanbay Batyr Ave., Astana 010000, Kazakhstan

5. Department of Chemistry, L.N. Gumilyov Eurasian National University, 2 Satpayev St., Astana 010008, Kazakhstan

6. School of Science and Technology, University of New England, Armidale, NSW 2351, Australia

Abstract

We herein report successful syntheses of both nickel cobalt sulfide (NCS) and its composite with zeolite (NCS@Z) using a solvothermal method. Techniques such as EDX analysis, SEM, and molar ratio determination were used for product characterization. The incorporation of NCS significantly changed the surface roughness and active sites of the zeolite, improving the efficiency of methylene blue degradation and its reusability, especially under UV irradiation. In comparing the pseudo-first order rates, the highest degradation efficiency of methylene blue was achieved with NCS-2@Z, having a degradation extent of 91.07% under UV irradiation. This environmentally friendly approach offers a promising solution for the remediation of methylene blue contamination in various industries.

Funder

Science Committee of the Ministry of Science and Higher Education of the Republic of Kazakhstan

Nazarbayev University under the Faculty Development Competitive Research Grants Program

Office of the Vice-Chancellor for Research and Extension, Mindanao State University—Iligan Institute of Technology

Publisher

MDPI AG

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