Synthesis of Coumarin-Based Photosensitizers for Enhanced Antibacterial Type I/II Photodynamic Therapy

Author:

Ma Min1,Luo Lili1,Liu Libing12ORCID,Ding Yuxuan1,Dong Yixuan1,Fang Bing12ORCID

Affiliation:

1. Department of Nutrition and Health, China Agricultural University, Beijing 100193, China

2. Key Laboratory of Precision Nutrition and Food Quality, China Agricultural University, Beijing 100193, China

Abstract

Photodynamic therapy (PDT) is an effective method for treating microbial infections by leveraging the unique photophysical properties of photosensitizing agents, but issues such as fluorescence quenching and the restricted generation of reactive oxygen species (ROS) under hypoxic conditions still remain. In this study, we successfully synthesized and designed a coumarin-based aggregation-induced emission luminogen (AIEgen), called ICM, that shows a remarkable capacity for type I ROS and type II ROS generation. The 1O2 yield of ICM is 0.839. The ROS it produces include hydroxyl radicals (HO•) and superoxide anions (O2•−), with highly effective antibacterial properties specifically targeting Staphylococcus aureus (a Gram-positive bacterium). Furthermore, ICM enables broad-spectrum fluorescence imaging and exhibits excellent biocompatibility. Consequently, ICM, as a potent type I photosensitizer for eliminating pathogenic microorganisms, represents a promising tool in addressing the threat posed by these pathogens.

Funder

Natural Science Foundation of China

Chinese Universities Scientific Fund

Publisher

MDPI AG

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