Effect of Polybutylene Succinate Additive in Polylactic Acid Blend Fibers via a Melt-Blown Process

Author:

Tangnorawich Benchamaporn12,Magmee Areerut3,Roungpaisan Nanjaporn4,Toommee Surachet5,Parcharoen Yardnapar26,Pechyen Chiravoot23

Affiliation:

1. Department of Physics, Faculty of Science and Technology, Thammasat University, Khlong Luang 12120, Thailand

2. Thammasat University Center of Excellence in Modern Technology and Advanced Manufacturing for Medical Innovation, Thammasat University, Khlong Luang 12120, Thailand

3. Department of Materials and Textile Technology, Faculty of Science and Technology, Thammasat University, Khlong Luang 12120, Thailand

4. Department of Textile Chemistry Engineering, Faculty of Engineering, Rajamangala University, Khlong Luang 12120, Thailand

5. Industrial Arts Program, Faculty of Industrial Technology, Kamphaeng Phet Rajabhat University, Mueang 62000, Thailand

6. Chulabhorn International College of Medicine, Thammasat University, Khlong Luang 12120, Thailand

Abstract

This work aimed to study the influence of the polybutylene succinate (PBS) content on the physical, thermal, mechanical, and chemical properties of the obtained polylactic acid (PLA)/PBS composite fibers. PLA/PBS blend fibers were prepared by a simple melt-blown process capable of yielding nanofibers. Morphological analysis revealed that the fiber size was irregular and discontinuous in length. Including PBS affected the fiber size distribution, and the fibers had a smoother surface with increased amounts of added PBS. Differential scanning calorimetry analysis (DSC) revealed that the crystallization temperature of the PLA sheet (105.8 °C) was decreased with increasing PBS addition levels down to 91.7 °C at 10 wt.% PBS. This suggests that the addition of PBS may affect PLA crystallization, which is consistent with the X-ray diffraction analysis that revealed that the crystallinity of PLA (19.2%) was increased with increasing PBS addition up to 28.1% at 10 wt% PBS. Moreover, adding PBS increased the tensile properties while the % elongation at break was significantly decreased.

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

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