Affiliation:
1. Department of Chemical Engineering, Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 05029, Republic of Korea
Abstract
Vitrimers, as dynamic covalent network polymers, represent a groundbreaking advancement in materials science. They excel in their applications, such as advanced thermal-conductivity composite materials, providing a sustainable alternative to traditional polymers. The incorporation of vitrimers into composite fillers enhances alignment and heat passway broadly, resulting in superior thermal conductivity compared to conventional thermosetting polymers. Their dynamic exchange reactions enable straightforward reprocessing, fostering the easy reuse of damaged composite materials and opening possibilities for recycling both matrix and filler components. We review an overview of the present advancements in utilizing vitrimers for highly thermally conductive composite materials.
Reference70 articles.
1. Silica-like Malleable Materials from Permanent Organic Networks;Montarnal;Science,2011
2. Vitrimers: Associative Dynamic Covalent Adaptive Networks in Thermoset Polymers;Krishnakumar;Chem. Eng. J.,2020
3. Biobased Vitrimers: Towards Sustainable and Adaptable Performing Polymer Materials;Lucherelli;Prog. Polym. Sci.,2022
4. Hammer, L., Van Zee, N.J., and Nicolaÿ, R. (2021). Dually Crosslinked Polymer Networks Incorporating Dynamic Covalent Bonds. Polymers, 13.
5. Multi-Functional Epoxy Vitrimers: Controllable Dynamic Properties, Multiple-Stimuli Response, Crack-Healing and Fracture-Welding;Chen;Compos. Sci. Technol.,2022