Application of Advanced Oxidation Processes for the Treatment of Color and Chemical Oxygen Demand of Pulp and Paper Wastewater

Abstract

The present study was conducted in order to investigate the efficiency of different advanced oxidation processes both individually and in combination with the biological method for the removal of color and chemical oxygen demand (COD) from wastewater in the pulp and paper industry. Advanced oxidation processes include ozone, Fenton, hydrogen peroxide, and photo-Fenton. Biologically treated wastewater was successively subjected to advanced oxidation processes (AOPs). The optimum conditions for the ozone treatment of raw wastewater were found to be a contact time of 9 min and a pH of 5 at a fixed dose of ozone for a removal efficiency of 41.22% for color and 88.53% for COD. Similar optimum conditions for the ozone treatment of biologically treated wastewater showed a removal efficiency of 46.36% for color and 95.92% for COD. The photo-Fenton process also showed an efficiency comparable to the ozone treatment for both raw wastewater and biologically treated wastewater, resulting in a removal efficiency of 39.85% (color) and 90.13% (COD) for raw wastewater, and of 41.34% (color) and 94.29% (COD) for biologically treated wastewater. Each had a contact time of 12 h. The Fenton oxidation of raw wastewater showed a removal efficiency of more than 26.30% for color and 86.33% for COD. Fenton oxidation, however, showed an efficiency of 26.62% for color and 84.49% for COD removal from biologically treated wastewater. Hydrogen peroxide showed an efficiency of 28.45% for color and 85.13% for COD removal from raw wastewater, and 39.48% for color and 86.53% for COD removal from biologically treated wastewater. The results for the raw wastewater treatments indicated that higher removal efficiencies can be achieved when they are used as pre-treatments. Biological treatment is a cost-effective method but it has less efficiency for color removal. In combination with one of the AOPs, either as a pre- or post-treatment under a controlled time and dose, biological treatment increased the efficiency, making treatment feasible at larger scales.