High Performance of Salt-Modified–LTO Anode in LiFePO4 Battery

Author:

Purwanto AgusORCID,Muzayanha Soraya Ulfa,Yudha Cornelius Satria,Widiyandari Hendri,Jumari Arif,Dyartanti Endah Retno,Nizam Muhammad,Putra Muhamad Iqbal

Abstract

Highly crystalline “zero-strain” Li4Ti5O12 (LTO) has great potential as an alternative material for the anodes in a lithium ion battery. In this research, highly crystalline LTO with impressive electrochemical characteristics was synthesized via a salt-assisted solid-state reaction using TiO2, LiOH, and various amounts of NaCl as a salt additive. The LTO particles exhibited a cubic spinel structure with homogenous micron-sized particles. The highest initial specific discharge capacity of LTO was 141.04 mAh/g with 4 wt % NaCl addition, which was tested in a full-cell (LTO/LiFePO4) battery. The battery cell showed self-recovery ability during the cycling test at 10 C-rate, which can extend the cycle life of the cell. The salt-assisted process affected the crystallinity of the LTO particles, which has a favorable effect on its electrochemical performance as anodes.

Funder

Kementerian Riset Teknologi Dan Pendidikan Tinggi Republik Indonesia

Publisher

MDPI AG

Subject

Fluid Flow and Transfer Processes,Computer Science Applications,Process Chemistry and Technology,General Engineering,Instrumentation,General Materials Science

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