Experimental and Theoretical Insight into Different Species of p-Aminothiophenol Adsorbed on Silver Nanoparticles

Author:

López-Ramírez María Rosa1,García-Gómez Laura2,Forte-Castro Arantxa3ORCID,Contreras-Cáceres Rafael3ORCID

Affiliation:

1. Department of Physical Chemistry, Faculty of Science, University of Málaga, 29071 Málaga, Spain

2. UMALASERLAB, Department of Analytical Chemistry, University of Málaga, C/ Jiménez Fraud 4, 29010 Málaga, Spain

3. Department of Chemistry and Physics, Faculty of Experimental Sciences, University of Almeria, 04120 Almería, Spain

Abstract

The adsorption of p-aminothiophenol (PATP) on metallic nanostructures is a very interesting phenomenon that depends on many factors, and because of that, PATP is an increasingly important probe molecule in surface-enhanced Raman spectroscopy (SERS) due to its strong interaction with Ag and Au, its intense SERS signal, and its significance in molecular electronics. In our study, the SERS spectra of PATP on silver colloids were investigated and we considered several factors, such as the effect of the adsorbate concentration, the nature of the metallic nanoparticles, and the excitation wavelength. Differences between the SERS spectra recorded at high and low concentrations of PATP were explained and DFT calculations of different species were performed in order to support the experimental results. Additionally, time-dependent density-functional theory (TD-DFT) calculations were used to simulate the UV spectra of each species and to determine the MOs involved in each transition. The presence of different species of PATP adsorbed onto the metal surface gave rise to the acquisition of simultaneous SERS signals from those species and the consequent overlapping of some bands with new SERS bands coming from the dimerization of PATP. This work helped to discern which species is responsible for each SERS spectrum under particular experimental conditions.

Funder

Ramón y Cajal

Publisher

MDPI AG

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