Copper and Zinc as Roofing Materials—A Review on the Occurrence and Mitigation Measures of Runoff Pollution

Abstract

Stormwater runoff from metal roofs has been a significant subject of discussion, especially when it comes to its treatment and the target concentrations that need to be achieved prior to discharge into the aquatic environment. To raise further awareness on this issue, occurrence, characterization, and also mitigation measures for metal roof runoff were analyzed using the example of copper and zinc roofs. These stormwater runoffs were found to contain metals in significant concentrations, mainly due to the wash-off of corrosion products by precipitation. Factors influencing metal corrosion and runoff concentrations were compiled. As Cu and Zn mainly occur in dissolved and thus bioavailable forms in roof runoff, harmful effects on the environment were detected. Therefore, adequate treatment of the runoff before discharge to groundwater or surface water is necessary to protect the aquatic environment. Vegetated infiltration swales as an sustainable urban drainage system enable a reduction in pollution loads. However, especially in densely built-up urban areas, stormwater quality improvement devices (SQIDs) offer an attractive alternative for pre-treating metal roof runoff, as they are mostly located underground. There is not yet a uniform legal approval system for SQIDs in Germany, but the German state of Bavaria has approved four types of SQIDs according to its own developed test criteria.