Salt Scaling Resistance of Variable w/c Ratio Air-Entrained Concretes Modified with Polycarboxylates as a Proper Consequence of Air Void System

Abstract

The values of the air void parameters in hardened concrete (spacing factor L ≤ 0.200 mm and micro air content A300 ≥ 1.5%), determined on the basis of the Powers model, in concretes produced today do not always guarantee the frost resistance of the concrete, especially when in surface impact with the participation of de-icing agents. The literature indicates that the modified polycarboxylates used to liquefy concrete mixes are one of the factors involved in changing the air void system; therefore, the aim of the article was to determine the dependence of the air void parameters and the resistance to scaling of concretes liquefied to a constant consistency by the use of modified polycarboxylates in the spectrum of variability of the ratio w/c = 0.53 ÷ 0.30. In the research program, twelve concrete mixes were made with a constant proportion of aggregate and paste: six air-entrained—with a constant air content of 5.5 ± 0.5%—and six non-air-entrained. The air void parameters were determined in accordance with EN 480-11, while the resistance to scaling was determined in accordance with CEN/TS 12390-9 and assessed according to the criteria of SS 137244. The analysis of the test results showed that liquefaction with modified polycarboxylates did not affect the w/c limit values, enabling obtaining concretes resistant to scaling. They are, respectively, 0.35 in the non-air-entrained concretes and 0.50 in the air-entrained concretes with an air content of 5.5 ± 0.5. Moreover, the commonly used criterion for ensuring the frost resistance of air-entrained concretes, L ≤ 0.200 mm and A300 ≥ 1.5%, requires supplementing with the minimum value of the w/c ≤ 0.50.