Affiliation:
1. Department of Chemistry, University of South Africa, P.O. Box 392, Pretoria 0003, South Africa
2. Department of Chemistry, University of Limpopo, Private Bag x1106, Sovenga 0727, South Africa
3. Analytical Chemistry Division (ACD), Council for Mineral Technology (Mintek) 200 Malibongwe Drive, Praegville, Randburg 2194, South Africa
4. Cape Point Global Atmosphere Watch Station, South Africa Weather Service, c/o CSIR, Stellenbosch 7599, South Africa
Abstract
It has been demonstrated that benzene, toluene, and xylene are carcinogens. Its combined effects with other contaminants have the potential to harm several ecosystem components. Since most human benzene exposure takes place inside, it is important to understand how outdoor benzene emissions from traffic and industry affect interior concentrations. However, this area of study has not received enough attention to date. Herein, we examine the outdoor concentrations of benzene, toluene, and xylene (BTX) in a Steelpoort mining area. BTX pollutants were passively sampled on the first seven days of the month, from January to December 2021 using Radiello samplers. The effects of meteorological parameters such as temperature, relative humidity, wind speed, and solar radiation on BTX concentrations were also statistically tested. For all seasons, BTX concentrations were greater in the winter than in the summer with concentrations of 0.69 µg/m3, 2.97 µg/m3 and 0.80 µg/m3 for benzene, toluene and xylene, respectively. In addition, toluene was the most common BTX compound with the highest concentrations when compared to benzene and xylene. Benzene, toluene and xylene, had yearly average concentrations of 0.61 µg/m3, 1.48 µg/m3 and 0.64 µg/m3, respectively. The benzene and xylene concentrations were below international exposure limits (annual, 5 µg/m3 for benzene; weekly, 260 µg/m3 for toluene), as in comparison to the World Health Organization, as well as within South African exceedance limits. Both positive and negative correlations between BTX and meteorological parameters were demonstrated by statistical models. Temperature, wind speed, and relative humidity depicted a weak negative correlation with benzene of 0.003, 0.019 and 0.006, respectively. Toluene showed a positive correlation with wind speed (1.90) and relative humidity (0.041). Overall, the concentration of benzene is of major concern since it is an agent of cancer and it is there in the atmosphere.
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