Affiliation:
1. College of Chemistry, Baicheng Normal University, Baicheng 137000, China
2. Institute of Green Chemistry and Chemical Technology, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
Abstract
Exploration of high-efficiency stabilization and abundant source-conjugated polymers semiconductor materials with suitable molecular orbital energy levels has always been a hot topic in the field of photocatalytic hydrogen evolution (PHE) from water splitting. In the recent years, constructing the intramolecular donor–acceptor (D–A)-conjugated architecture copolymers has been proved as one of the most excellent photocatalyst modification tactics for optimizing the PHE properties because of unique advantages, including easy regulate band-gap position, fast transfer charge carrier in the intramolecular architecture, superior sunlight absorption capacity and range, large interfacial areas, and so forth. Therefore, in this minireview, we summarize the latest research progress of D–A architecture semiconductor materials for PHE from water splitting. First, we briefly overview the fundamental description and principles for the construction D–A heterostructures in the photocatalytic system. After that, the application of D–A architecture photocatalyst for PHE reaction over different classes of organic semiconductors have been discussed in detail. At last, the present development prospects and future potential challenges of D–A architecture materials are proposed. We hope this minireview has some parameter values for the further developments of intermolecular special structured organic semiconductor material in the future PHE research.
Funder
the National Natural Science Foundation of China
the Natural Science Foundation of Jiangsu Province
the Postdoctoral Science Foundation of China
Innovation and Entrepreneurship training Program for college students of Jilin Province
Subject
Physical and Theoretical Chemistry,Catalysis,General Environmental Science
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献