The Analysis of Red Lead Endsheets in Rare Books from the Fung Ping Shan Library at the University of Hong Kong

Abstract

Stored under optimal conditions, paper can last for hundreds of years; however, paper is also susceptible to numerous agents of deterioration as it is primarily made of cellulose fibre derived from plant cell walls. Paper is especially vulnerable under conditions with high temperature and humidity, which together can encourage mould growth and foster insect pests. Pest infestation is a common type of deterioration responsible for significant damage to paper and books. Endsheets prepared with red lead and sewn into traditional Chinese bookbindings are a historical method used to minimise insect damage to books in southern China. Samples of red-coloured papers from the Fung Ping Shan Library at the University of Hong Kong were assessed. Two types of so called wan nian hong papers (萬年紅紙), (1) damaged and (2) undamaged by insects, were analysed with a scanning electron microscope equipped with an energy dispersive X-ray fluorescence detector. The chemical analyses reveal high concentrations of red lead (lead tetroxide, Pb3O4) in the undamaged papers, and only very few traces of lead in the damaged papers. The orange papers with insect feeding tunnels seem to have been only coloured in orange, and not treated with red lead as a biocide. These results are discussed and compared with modern treatment methods in the integrated pest management of books, archive, and library materials in (a) Europe and (b) Asia.