The Influence of Retreated Lithium Slag with a High Content of Alkali, Sulfate and Fluoride on the Composition and the Microstructure of Autoclaved Aerated Concrete

Author:

Zhong Dongqing1,Wei Shihong1,Zhou Hao2ORCID,He Xiaohang1,Qian Binbin3,Ma Bing2,Hu Yueyang14,Ren Xuehong4

Affiliation:

1. College of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224000, China

2. Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment of the People’s Republic of China, Nanjing 210042, China

3. School of Chemistry and Environmental Engineering, Yancheng Teachers University, Yancheng 224002, China

4. State Key Laboratory of Green Building Materials, China Building Materials Academy, Beijing 100024, China

Abstract

In this paper, the possibility of retreated lithium slag (RTLS) with a high content of alkali, sulfate and fluoride as a partial replacement for fly ash (FA) to produce autoclaved aerated concrete (AAC) was investigated. The influence of the RTLS dosage on the AAC performance were examined. The composition and microstructure of hydrates as well as the microstructure of the RTLS-FA-based AAC compositions were determined by XRD, FTIR, TG-DSC and SEM. The results illustrated that the incorporation of RTLS changed the crystal structure and the microstructure of the tobermorite. With increased RTLS contents, the morphology of tobermorite was changed, and the grass-like tobermorite gradually transformed into network-like tobermorite. The newly formed tobermorite improved the mechanical performance of the AAC. Compared with the RTLS10, the content of tobermorite in the RTLS30 increased by 8.6%.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province of China

Jiangsu Provincial Key Research and Development Project

Postgraduate Research and Practice Innovation Program of Yancheng Institute of Technology

special fund project for transformation of scientific and the special fund project for the development of strategic emerging industries in Jiangsu Province

Publisher

MDPI AG

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