Structural Motifs in Aryl Organogermanium Ge-O Derivatives for Material Design-Reference-Cited by-同舟云学术

Structural Motifs in Aryl Organogermanium Ge-O Derivatives for Material Design

Published:2023-09-01 Issue:17 Volume:24 Page:13575
ISSN:1422-0067
Container-title:International Journal of Molecular Sciences
language:en
Short-container-title:IJMS

Author:

Zaitsev Kirill V.¹^ORCID,Makarov Igor S.²^ORCID,Oprunenko Yuri F.¹,Tafeenko Victor A.¹,Lermontova Elmira Kh.³,Churakov Andrei V.³^ORCID

Affiliation:

1. Chemistry Department, M.V. Lomonosov Moscow State University, Leninskye Gory 1, 3, Moscow 119991, Russia

2. A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky Pr. 29, Moscow 119991, Russia

3. N.S. Kurnakov General and Inorganic Chemistry Institute, Russian Academy of Sciences, Leninskii Pr. 31, Moscow 119991, Russia

Abstract

The aim of this work was to understand the main structural features and ways of formation of Ge-O bonds in organogermanium compounds under the conditions of ArnGeHal4-n (Hal = halide) hydrolysis. The structural types of these compounds were considered, providing 11 blocks (A–K). The molecular structures of the novel compounds [(p-FC6H4)3Ge]2O (1), [(p-F3CC6H4)3Ge]2O (2), and cyclo-[(p-F3CC6H4)2GeO]4 (3) were studied through XRD (X-ray diffraction) analysis. The molecular structure of [(p-F3CC6H4)3GeO]4Ge (4), representing a novel structural type, was also investigated. The data presented in this study will be important in the design of materials with useful properties based on group 14 element derivatives with element–oxygen bonding.

Funder

President of the Russian Federation for the Support of Young Scientists

Publisher

MDPI AG

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Computer Science Applications,Spectroscopy,Molecular Biology,General Medicine,Catalysis

Link

https://www.mdpi.com/1422-0067/24/17/13575/pdf

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