Intensification of Sulfuric Acid Leaching of Altered Ilmenite via Adding Fluoride Activator

Author:

Dubenko Anastasiia V.ORCID,Nikolenko Mykola V.ORCID,Pasenko Oleksandr O.,Kostyniuk AndriiORCID,Likozar BlažORCID

Abstract

A new method of altered ilmenite processing has been studied. In this method, sulfuric acid is used as the reaction medium of the process, and fluoride ions are activators of the dissolving process of the rutile part of the ore raw material. The regression model of the sulfate–fluoride leaching process was developed and analyzed by using the response surface method of 23 matrix. The obtained model is adequate and well describes the studied process. The influence of Ti:F molar ratio, temperature, and sulfuric acid concentration on the leaching process are investigated in this work in order to optimize the studied process. It is experimentally proved that leaching at temperatures above 100 °C, at a molar ratio of Ti:F of more than 1:2, and the use of solutions of sulfuric acid with concentrations of more than 85 wt.% is not optimal because the extraction degree of titanium is reduced. The intensification of the process of sulfuric acid leaching by dividing the main stage of chemical dissolution of ilmenite into two stages was proposed. This method allows to leach up to 95.9% of titanium, which is 1.6–1.9 times higher in comparison with the classical technology of leaching altered ilmenite.

Publisher

MDPI AG

Subject

Process Chemistry and Technology,Chemical Engineering (miscellaneous),Bioengineering

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