Spatiotemporal Distribution of PM2.5 and O3 and Their Interaction During the Summer and Winter Seasons in Beijing, China

Abstract

This study analyzed the spatiotemporal variations in PM2.5 and O3, and explored their interaction in the summer and winter seasons in Beijing. To this aim, hourly PM2.5 and O3 data for 35 air quality monitoring sites were analyzed during the summer and winter of 2016. Results suggested that the highest PM2.5 concentration and the lowest O3 concentration were observed at traffic monitoring sites during the two seasons. A statistically significant (p < 0.05) different diurnal variation of PM2.5 was observed between the summer and winter seasons, with higher concentrations during daytime summer and nighttime winter. Diurnal variations of O3 concentrations during the two seasons showed a single peak, occurring at 16:00 and 15:00 in summer and winter, respectively. PM2.5 presented a spatial pattern with higher concentrations in southern Beijing than in northern areas, particularly evident during wintertime. On the contrary, O3 concentrations presented a decreasing spatial trend from the north to the south, particularly evident during summer. In addition, we found that PM2.5 concentrations were positively correlated (p < 0.01, r = 0.57) with O3 concentrations in summer, but negatively correlated (p < 0.01, r = −0.72) with O3 concentrations in winter.