Facile Synthesis of Ag-Doped Urchin-like MnO2 on Carbon Cloth for Supercapacitors

Author:

Feng Yanqiu12,Qu Henghui2,Wang Yanxiang1,Wang Lanzhong3,Wang Yongbo1,Yang Deli1,Ding Bohan1,Sun Yue1,Guo Jinghe1,Dai Shichao1

Affiliation:

1. Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, China

2. Shandong Hi-Speed Materials Technology Development Co., Ltd., Jinan 250014, China

3. School of Foreign Languages and Literature, Shandong University, Jinan 250100, China

Abstract

Based on MnO2/carbon cloth (CC) composite materials, an Ag-doped MnO2 nanowire, self-assembled, urchin-like structure was synthesized in situ on the surface of CC using a simple method, and a novel and efficient flexible electrode material for supercapacitors was developed. The morphology, structure, elemental distribution, and pore distribution of the material were analyzed using SEM, TEM, XRD, XPS, and BET. The electrochemical performance was tested using cyclic voltammetry (CV) and galvanostatic charge/discharge (GCD). In the three-electrode system, GCD testing showed that the specific capacitance of the material reached 520.8 F/g at 0.5 A/g. After 2000 cycles at a current density of 1 A/g, the capacitance retention rate was 90.6%, demonstrating its enormous potential in the application of supercapacitor electrode materials.

Funder

Natural Science Foundation of Shandong Province

key research and development program of Shandong Province

Publisher

MDPI AG

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