The Use of Nonmetallic Fraction Particles with the Double Purpose of Increasing the Mechanical Properties of Low-Density Polyethylene Composite and Reducing the Pollution Associated with the Recycling of Metals from E-Waste

Author:

Flores-Campos Rubén1ORCID,Deaquino-Lara Rogelio2ORCID,Rodríguez-Reyes Mario3,Martínez-Sánchez Roberto45ORCID,Estrada-Ruiz Rosa Hilda3ORCID

Affiliation:

1. Departamento de Metal-Mecánica, I. T. Saltillo (ITS)/Tecnológico Nacional de México, Venustiano Carranza No. 2400, Col. Tecnológico, Saltillo C.P. 25280, Mexico

2. Centro de Investigación y de Estudios Avanzados Unidad Saltillo, Carretera Saltillo-Monterrey Km 13, Col. Molinos del Rey, Ramos Arizpe C.P. 25900, Mexico

3. División de Estudios de Posgrado e Investigación, I. T. Saltillo (ITS)/Tecnológico Nacional de México, Venustiano Carranza No. 2400, Col. Tecnológico, Saltillo C.P. 25280, Mexico

4. Centro de Investigación en Materiales Avanzados, S.C. (CIMAV), Av. Miguel de Cervantes #120, Complejo Industrial Chihuahua, Chihuahua C.P. 31136, Mexico

5. Instituto de Metalurgia, Universidad Autónoma de San Luis Potosí (UASLP), Sierra Leona No. 550, San Luis Potosí C.P. 78210, Mexico

Abstract

A restorative process, where the nonmetallic fraction from e-waste printed circuit boards is reused as a raw material for the conformation of a new polymer matrix composite with increased properties favoring its industrial applications, is proposed with a zero residues approach. Low density polyethylene pellets and nonmetallic fraction particles were mixed, and due to the generation of static electricity during the mixing process, the nonmetallic particles became attached to the polyethylene pellets; the blended material was fed into a screw extruder, producing filaments of the new composite. Mechanical properties increased as the particles content increased, presenting an ultimate tensile strength going from 20 for the raw low-density polyethylene to more than 60 MPa, and a yield strength that goes from 10 to 50 MPa on the composite with 6.0 wt.% particles. Also, the flammability of the composite improved, reducing its linear burning rate and increasing the time between detachment of two consecutive drops. Nonmetallic fraction particles were oriented in the extrusion direction and had a good adhesion with the polyethylene matrix. These composites can be employed for the production of prototypes using additive manufacture.

Funder

Tecnológico Nacional de México

Publisher

MDPI AG

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