Corrosion Inhibition of Aluminum in Acidic Solution by Ilex paraguariensis (Yerba Mate) Extract as a Green Inhibitor

Author:

Méndez Claudia M.12ORCID,Gervasi Claudio A.34,Pozzi Gonzalo1,Ares Alicia E.12ORCID

Affiliation:

1. Programa de Materiales y Fisicoquímica, Facultad de Ciencias Exactas, Químicas y Naturales, Universidad Nacional de Misiones, Félix de Azara 1552, Posadas 3300, Argentina

2. Instituto de Materiales de Misiones—Consejo Nacional de Investigaciones Científicas y Técnicas, Facultad de Ciencias Exactas, Químicas y Naturales, Universidad Nacional de Misiones, Félix de Azara 1552, Posadas 3300, Argentina

3. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas—Consejo Nacional de Investigaciones Científicas y Técnicas, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, Diagonal 113 y 64 S/N, La Plata 1900, Argentina

4. Area Electroquímica, Facultad de Ingeniería, Universidad Nacional de La Plata, Av. 1 750, La Plata 1900, Argentina

Abstract

In the present work, the inhibitory effect of Ilex paraguariensis (Yerba Mate) extract on the corrosion of aluminum in 0.1 M HCl solution, in the temperature range of 298–323 K, was studied by using weight loss tests, potentiodynamic polarization measurements and electrochemical impedance spectroscopy (EIS). The extract of Ilex paraguariensis exhibits improved inhibitory action as its concentration increases while its performance is maintained despite an increase in temperature. EIS theoretical data according to a suitable proposed equivalent circuit were successfully fitted to the experimental data. The adsorption of organic compounds followed a modified Langmuir isotherm behaviour. Derived thermodynamic parameters indicate the occurrence of both chemical and physical adsorption.

Funder

Consejo Nacional de Investigaciones Científicas y Técnicas

Agencia Nacional de Promoción Científica y Tecnológica

Publisher

MDPI AG

Subject

Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces

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