Investigating the Potential of the Er:YAG Laser for the Removal of Cemented Dust from Limestone and Painted Plaster

Abstract

A successful application of Er:YAG laser for the cleaning of a restored Assyrian relief sculpture from the British Museum collection is presented. Displayed in the gallery, the sculpture has darkened over time due to the natural deposition of dirt, in particular on restored parts. Since traditional cleaning methods have demonstrated to be unsuccessful, a scientific investigation was performed to identify the composition of the soiling and the materials used for the restoration. The analysis suggested the presence of gypsum, calcium oxalate, carbonates and alumino-silicates on the encrustation. The molded plaster, composed of lime and gypsum and pigmented aggregates, was likely prepared at the end of the 19th century to mimic the stone color. It was repainted with what was identified as a modern oil-based overpaint, applied to cover darkening during a second conservation treatment in the 20th century. Laser trials were first performed on small areas of the objects and on mock-ups to determine the critical fluence thresholds of the surface, investigated through visual examination and analyses using Fourier transform infrared spectroscopy (FTIR) and Pyrolysis-gas chromatography-mass spectrometry (Py–GC–MS). The right parameters and conditions to be used during the cleaning process were, therefore, determined. The chemical selectivity of the cleaning process allowed us to complete the treatment safely while preserving the restoration.