Coating on Steel Discs with a Photocatalytic System CuO/SiO2 for the Degradation of the Ubiquitous Contaminants Methylene Blue and Amoxicillin

Author:

Hernández-Reyes Alberto1,Lijanova Irina V.1ORCID,Garrido-Hernández Aristeo2,Morales-Ramirez Ángel de J.1,Hernández-Fuentes Carlos13,Calvillo-Muñoz Evelyn Y.4ORCID,Likhanova Natalya V.4ORCID,Olivares-Xometl Octavio5ORCID

Affiliation:

1. Centro de Investigación e Innovación Tecnológica, Instituto Politécnico Nacional, Ciudad de México 02250, Mexico

2. División Químico Biológicas, Universidad Tecnológica de Tecámac, Tecámac, Estado de México 55740, Mexico

3. Escuela Superior de Ingeniería Mecánica y Eléctrica, Instituto Politécnico Nacional, Av. Luis Enrique Erro S/N, Unidad Profesional Adolfo López Mateos, Zacatenco, Delegación Gustavo A. Madero, Ciudad de México 07738, Mexico

4. Instituto Mexicano del Petróleo, Eje Central Norte Lázaro Cárdenas No. 152, Col. San Bartolo Atepehuacan, G. A. Madero, Ciudad de México 07730, Mexico

5. Facultad de Ingeniería Química, Benemérita Universidad Autónoma de Puebla, Av. San Claudio y 18 Sur, Ciudad Universitaria, Col. San Manuel, Puebla 72570, Mexico

Abstract

The present research work describes the synthesis and characterization of CuO/SiO2 for coating-perforated 304 stainless steel (SS) substrates to degrade methylene blue and amoxicillin under visible light irradiation. The foregoing photocatalytic system was achieved through the coprecipitation method by adding pure CuO to a SiO2 sol at 1:5, 1:10, and 1:15 molar ratios. The conditions for carrying out the depositions on the SS substrates (three per substrate) involved an immersion rate of 90 mm/min with a drying time of 20 min at 120 °C. The XRD technique confirmed the presence of the SiO2 amorphous phases and CuO monoclinic systems in the coatings, with a particle size distribution ranging from 0.5 to 2.5 μm (with an average of 1.26 ± 0.06 μm). As for SEM, it revealed a homogeneous coating surface without cracks. The produced photoactive CuO/SiO2 coatings were capable of degrading methylene blue (98%) at 1500 min and amoxicillin (55%) at 450 min.

Funder

CONACYT

SIP-IPN

Publisher

MDPI AG

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