Effects of the Ratio of Nano-Cu to Hydroxylated MWCNTs on Anticorrosion and Surface Conductivity of Cu/MWCNT Epoxy Coatings on a Steel Substrate

Abstract

Epoxy coatings provide an economical and practical solution for combating steel corrosion. However, epoxy coatings have poor conductivity, resulting in the accumulation of electrostatic charges. The surface conductivity and anticorrosion properties of epoxy coatings can be improved by adding nano-Cu and hydroxylated multi-walled carbon nanotubes (MWCNTs). This paper investigates the impact of MWCNTs at different concentrations (2.5, 5%) and the ratio of nano-Cu to MWCNTs on the surface conductivity and anticorrosion properties of epoxy coatings on a steel substrate. The findings from the four-probe method of measuring surface resistance indicated that the surface resistivity of steel coated with an epoxy composite of 5% MWCNTs and 65% nano-Cu (Cu65/MWCNT5) was significantly lower, approximately by one order of magnitude, compared to steel coated with a 5% MWCNT (MWCNT5) epoxy coating. When the Cu65/MWCNT5-coated steel was immersed in a 3.5 wt % NaCl solution for 30 days, it was observed that there was a minimal effect on its surface resistivity. The inclusion of a high content of MWCNTs facilitates a more uniform distribution of Cu particles within the epoxy coatings, thereby improving the anticorrosion properties of these coatings on a steel substrate. This was further corroborated by the results of the polarization curves and electrochemical impedance spectroscopy, demonstrating that the Cu65/MWCNT5 epoxy coating on a steel substrate offers exceptional anticorrosion and barrier protection properties. The corrosion rate of steel with a Cu65/MWCNT5 epoxy coating was three orders of magnitude lower than that of steel with a Cu65/MWCNT2.5 epoxy coating, at 4.79 × 10−7 mm/year.