The Modification of Aluminum Oxide Inclusions in Bearing Steel under Different Cleanliness Conditions by Rare Earth Elements

Abstract

The impact of rare earth treatment on the chemical morphology evolution of non-metallic inclusions in bearing steel under different initial cleanliness conditions was studied through simulation. Thermodynamic calculations indicate that at an oxygen content of 0.001%, the evolution route of inclusions with increasing Ce content was Al2O3 → CeAl11O18 + CeAlO3 → CeAlO3 + Ce2O2S → Ce2O2S → Ce2O2S + CeS. As the initial oxygen content decreases, the proportion of CeAlO3 decreases, leading to easier conversion of CeAlO3 to Ce2O2S. Vacuum induction furnace experiments demonstrated that with an oxygen content of 0.001%, an increase in Ce content results in a gradual rise in the proportion of inclusions in steel sized 1~2 μm. In contrast, the proportion of inclusions sized 2~5 μm decreases. Consequently, the overall content of inclusions in steel decreases, along with a reduction in both the number density and average size of inclusions. Introducing bearing steel melt with approximately 0.01% Ce rare earth to bearing steel with initial oxygen contents of 0.0005%, 0.001%, and 0.0015% showed an evolution of inclusions from Ce2O2S and CeS to Ce2O3, CeAlO3, etc. The average inclusion size significantly increased from 0.7 μm to 2.16 μm. Morphologically, the transition of inclusions from precipitated to polymerized forms occurred as the initial oxygen content rose. High-temperature laser confocal microscopy experiments demonstrated that inclusions in low cleanliness conditions tend to agglomerate more than those in high cleanliness conditions, contributing to the increase in average size.