Zn(II) Three-Dimensional Metal-Organic Frameworks Based on 2,5-Diiodoterephthalate and N,N Linkers: Structures and Features of Sorption Behavior-Reference-Cited by-同舟云学术

Zn(II) Three-Dimensional Metal-Organic Frameworks Based on 2,5-Diiodoterephthalate and N,N Linkers: Structures and Features of Sorption Behavior

Published:2023-04-28 Issue:5 Volume:11 Page:192
ISSN:2304-6740
Container-title:Inorganics
language:en
Short-container-title:Inorganics

Author:

Zaguzin Alexander S.¹²^ORCID,Sukhikh Taisiya¹^ORCID,Sokolov Maxim N.¹^ORCID,Fedin Vladimir P.¹^ORCID,Adonin Sergey A.¹²³

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry SB RAS, 630090 Novosibirsk, Russia

2. South Ural State University, 454080 Chelyabinsk, Russia

3. Favorsky Irkutsk Institute of Chemistry SB RAS, 664033 Irkutsk, Russia

Abstract

Two new coordination polymers based on Zn(II) and 2,5-diiodoterephthalate—{[Zn(2,5-I-bdc)bpe}] (1) and {[Zn(2,5-I-bdc)bpen}] (2)—were synthesized and characterized. Polymers 1 and 2 feature halogen bonding between the I atoms of MOF and DMF guest molecules, which plays a crucial role in structure stabilization. Selectivity of sorption towards different organic substrates was examined.

Funder

Russian Science Foundation

Ministry of Science and Higher Education of the Russian Federation

Publisher

MDPI AG

Subject

Inorganic Chemistry

Link

https://www.mdpi.com/2304-6740/11/5/192/pdf

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