Evaluation of Low-Toxic Hybrid Sol-Gel Coatings with Organic pH-Sensitive Inhibitors for Corrosion Protection of AA2024 Aluminium Alloy

Author:

Jaldo Serrano Eva1,López-Sánchez Jesús2ORCID,García-Galván Federico3ORCID,Serrano Aida2ORCID,Rodríguez de la Fuente Óscar14,Barranco Violeta5,Galván Juan Carlos5ORCID,Carmona Noemí14ORCID

Affiliation:

1. Departamento de Física de Materiales, Facultad de Ciencias Físicas, Universidad Complutense de Madrid, Plaza Ciencias SN, 28040 Madrid, Spain

2. Instituto de Cerámica y Vidrio (ICV-CSIC), C/Kelsen 5, Campus de Cantoblanco, 28049 Madrid, Spain

3. Department of Engineering, School of Architecture, Engineering and Design, Universidad Europea de Madrid, 28670 Villaviciosa de Odón, Spain

4. Instituto de Magnetismo Aplicado (IMA) “Salvador Velayos”, A6 Km 22,5, 28230 Las Rozas Madrid, Spain

5. Centro Nacional de Investigaciones Metalúrgicas (CENIM-CSIC), Avda. Gregorio del Amo 8, 28040 Madrid, Spain

Abstract

Today’s environmental needs require the reduction of the weight of vehicles, thus reducing fuel consumption and associated emissions. For this reason, the use of light alloys is being studied, which, due to their reactivity, must be protected before use. In this work, the effectiveness of a hybrid sol-gel coating doped with various organic environmentally friendly corrosion inhibitors applied to an AA2024 lightweight aluminium alloy is evaluated. Some of the inhibitors tested are pH indicators, acting as both corrosion inhibitors and optical sensors for the surface of the alloy. Samples are subjected to a corrosion test in a simulated saline environment and characterised before and after the test. The experimental results regarding their best inhibitor performance for their potential application in the transport industry are evaluated.

Funder

Spanish Ministry of Science and Innovation

Spanish Ministry of Economic Affairs and Digital Transformation

MCIN for a “Ramón y Cajal”

Publisher

MDPI AG

Subject

Polymers and Plastics,Organic Chemistry,Biomaterials,Bioengineering

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