Recent Progress on Covalent Organic Frameworks Supporting Metal Nanoparticles as Promising Materials for Nitrophenol Reduction

Author:

Dinari Mohammad1ORCID,Golshadi Zaynab1,Asadi Parvin2,Norton Amie E.3,Reid Katelyn R.4,Karimi Benson4ORCID

Affiliation:

1. Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Iran

2. Department of Medicinal Chemistry, School of Pharmacy and Pharmaceutical Sciences, Isfahan University of Medical Sciences, Isfahan 81746-73461, Iran

3. Department of Entomology, Kansas State University, 123 W Waters Hall, 1603 Old Claflin Place, Manhattan, KS 66503, USA

4. Department of Physical and Environmental Sciences, Texas A&M University Corpus Christi, Corpus Christi, TX 78412, USA

Abstract

With the utilization of nitrophenols in manufacturing various materials and the expansion of industry, nitrophenols have emerged as water pollutants that pose significant risks to both humans and the environment. Therefore, it is imperative to convert nitrophenols into aminophenols, which are less toxic. This conversion process is achieved through the use of noble metal nanoparticles, such as gold, silver, copper, and palladium. The primary challenge with noble metal nanoparticles lies in their accumulation and deactivation, leading to a decrease in catalyst activity. Covalent organic frameworks (COFs) are materials characterized by a crystalline structure, good stability, and high porosity with active sites. These properties make them ideal substrates for noble metal nanoparticles, enhancing catalytic activity. This overview explores various articles that focus on the synthesis of catalysts containing noble metal nanoparticles attached to COFs as substrates to reduce nitrophenols to aminophenols.

Funder

Welch Foundation

Isfahan University of Technology

Publisher

MDPI AG

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