Proven Anti-Wetting Properties of Molybdenum Tested for High-Temperature Corrosion-Resistance with Potential Application in the Aluminum Industry

Abstract

The behavior of Mo in contact with molten Al was modelled by classical molecular dynamics (CMD) simulation of a pure Mo solid in contact with molten Al at 1200 K using the Materials Studio®. Results showed that no reaction or cross diffusion of atoms occurs at the Mo(s)–Al(l) interface, and that molten Al atoms exhibit an epitaxial alignment with the exposed solid Mo crystal morphology. Furthermore, the two phases {Mo(s) and Al(l)} are predicted to interact with weak van der Waals forces and give interfacial energy of about 203 mJ/m2. Surface energy measurements by the sessile drop experiment using the van Oss–Chaudhury–Good (VCG) theory established a Mo(s)–Al(l) interface energy equivalent to 54 mJ/m2, which supports the weak van der Waals interaction. The corrosion resistance of a high purity (99.97%) Mo block was then tested in a molten alloy of 5% Mg mixed in Al (Al-5 wt.%Mg) at 1123 K for 96 h, using the ALCAN’s standard “immersion” test, and the results are presented. No Mo was found to be dissolved in the molten Al-Mg alloy. However, a 20% mass loss in the Mo block was due to intergranular corrosion scissoring the Mo block in the ALCAN test, but not as a result of the reaction of pure Mo with the molten Al-Mg alloy. It was observed that the Al-Mg alloy did not stick to the Mo block.