Different Diacetyl Perception Detected through MOX Sensors in Real-Time Analysis of Beer Samples

Author:

Liboà Aris1ORCID,Genzardi Dario2ORCID,Núñez-Carmona Estefanía2ORCID,Carabetta Sonia3,Di Sanzo Rosa3,Russo Mariateresa3,Sberveglieri Veronica24ORCID

Affiliation:

1. Department of Chemistry, Life Science and Environmental Sustainability, University of Parma, Parco Area delle Scienze, 11/a, 43124 Parma, Italy

2. National Research Council, Institute of Bioscience and Bioresources (CNR-IBBR), Via J.F. Kennedy, 17/i, 42124 Reggio Emilia, Italy

3. Department of Agriculture Science, Food Chemistry, Safety and Sensoromic Laboratory (FoCuSS Lab), University of Reggio Calabria, Via dell’Università, 25, 89124 Reggio Calabria, Italy

4. Nano Sensor Systems, NASYS Spin-Off University of Brescia, 25125 Brescia, Italy

Abstract

Beer is the most consumed alcoholic beverage; with 177.5 million kiloliters produced every year, it is one of the most relevant food products. Diacetyl is a typical byproduct of yeast metabolism that is formed during the fermentation inside breweries. The perception of this high volatile and butter-like flavor molecule varies according to the kind of beer, from a positive and highly sought characteristic to a characteristic that is avoided. Furthermore, its toxicity when inhaled has been proven. Typical diacetyl analysis includes voltametric detection and chromatographic analysis techniques. Using metal oxide sensors (MOS), this analysis can become fast and cost-effective, evaluating the differences in diacetyl concentrations through resistance variation. The S3+ (Nano Sensor Systems s.r.l.; Reggio Emilia, Italy; device can recognize volatile compounds through a tailormade array of different materials. The results can be shown on a PCA that is directly generated by the instruments and can be used to manage the productive process through an IoT integrated system. Testing different beer typology through electrochemical sensors allows for the validation of this new approach for diacetyl evaluation. The results have shown an excellent ability to detect diacetyl in different beer samples, perfectly discriminating among different concentrations.

Funder

Italian Ministry of Research

Publisher

MDPI AG

Subject

Physical and Theoretical Chemistry,Analytical Chemistry

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