Effects of NH4SCN Additive in the FAPbI3 Perovskite Films in a Sequential Deposition Method

Author:

Miró-Zárate Jorge Luis1ORCID,Elías-Espinosa Miltón Carlos1ORCID,Cervantes-Sodi Felipe2ORCID,Diliegros-Godines Carolina Janani3ORCID

Affiliation:

1. Instituto Tecnologico y de Estudios Superiores de Monterrey, Campus Santa Fe, School of Engineering and Science, Mexico City 01389, Mexico

2. Physics and Mathematics Department, Universidad Iberoamericana Ciudad de Mexico, Prolongación Paseo de la Reforma 880, Mexico City 01219, Mexico

3. Instituto de Física, Benemérita Universidad Autónoma de Puebla, Apdo. Post. J-48, Puebla 72570, Pue, Mexico

Abstract

This study determined the effect of introducing the NH4SCN additive in the precursor solution of PbI2 of a sequential deposition method in an open atmosphere to form FAPbI3 perovskite over a glass substrate. Adding NH4SCN leads to different intermediate layers according to the concentration of the additive. From an adequate concentration, an ionic substitution between I− and SCN− is promoted, providing a unique path for nucleation and growth of FAPbI3 due to significant changes in morphology. The intermediate layer with a proper amount of NH4SCN enhanced the physical properties of FAPbI3. It contributed to understanding the crystallinity and morphological conditions for favorable growth of FAPbI3 directly over a glass substrate. A concentration of 40% gave rise to the biggest grain size, homogeneous morphology, higher absorption, and prevalence of black phase in the α/δ phase coexistence. As a result, the perovskite with the NH4SCN additive showed a positive effect on the growth mechanisms and enhanced stability due to the mixed α/δ-phase and grain size ∼1350 nm. The preceding makes FAPbI3 film with a concentration of 40% a good option for application as stable perovskite in solar cells.

Funder

Mexican government institution CONACyT

CONACYT Synergy project

FICSAC and FISMAT at Universidad Iberoamericana Ciudad de Mexico

VIEP-BUAP 2023

Publisher

MDPI AG

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering

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