Induced Birefringence by Drop Cast in EFBG Ammonia Sensors

Abstract

In this paper, an induced birefringence was observed on an ammonia sensor based on an etched fiber Bragg grating (EFBG) coated with an organic film. The film was prepared with a solution of the perylene derivative, along with the copolymer PCDTBT in chlorobenzene. The EFBG was coated by drop cast technique, and a split in the reflection band, characteristic of birefringence, was observed after deposition. The response of the two observed peaks as a function of time was modeled by a pair of exponentials that could represent two processes: adsorption followed by diffusion of the gas molecules in the microstructured film. Such phenomena alter the boundary conditions of the optical fiber propagating mode, which allows an indirect ammonia detection by monitoring the EFBG wavelength shift of the reflected peaks. The sensor was experimentally tested in a concentration range from 3 ppm to 41,700 ppm, and the calibrations curves were determined in a range from 27 ppm to 6960 ppm. The two observed peaks showed different sensitivities, which presents an intrinsic potential for multiparameter measurements. The split in the reflection band was hypothesized to be birefringence induced by the formation of an asymmetric film. This hypothesis was numerically evaluated and compared with the experimental results.