Author:
Liu Hao,Zhu Yongchang,Huo Jichuan,Cui Zhu,Zhang Xingquan,Jiang Qin,Yang Debo,Meng Baojian
Abstract
In this paper, the effect of doping phosphorus in a borosilicate glass matrix to improve the solubility of Mo was investigated by X-ray diffraction (XRD), Raman, and solid-state nuclear magnetic resonance (NMR) spectroscopy, and the effectiveness of Na content on P species inhibiting the growth of the crystallization of Mo was assessed. The results indicate that phosphate-doped borosilicate glass can host 4 mol% of Mo, and that such a borosilicate glass matrix could only accommodate 1 mol% of Mo without phosphate doping. The effectiveness of phosphorus may be correlated with the Na content in borosilicate glass, and a high Na content borosilicate glass matrix requires more P doping to accommodate Mo. In addition, incorporating large amounts of P can compromise the aqueous durability of the glass matrix.
Funder
Longshan academic talent research supporting program of Southwest University of Science and Technology
National Natural Science Foundation of China
Subject
General Materials Science
Cited by
3 articles.
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