Abstract
We evaluated the transport properties of a bacterial cellulose (BC) membrane for aqueous ethanol solutions. Using the Rr version of the Kedem–Katchalsky–Peusner formalism (KKP) for the concentration polarization (CP) conditions of solutions, the osmotic and diffusion fluxes as well as the membrane transport parameters were determined, such as the hydraulic permeability (Lp), reflection (σ), and solute permeability (ω). We used these parameters and the Peusner (Rijr) coefficients resulting from the KKP equations to assess the transport properties of the membrane based on the calculated dependence of the concentration coefficients: the resistance, coupling, and energy conversion efficiency for aqueous ethanol solutions. The transport properties of the membrane depended on the hydrodynamic conditions of the osmotic diffusion transport. The resistance coefficients R11r, R22r, and Rdetr were positive and higher, and the R12r coefficient was negative and lower under CP conditions (higher in convective than nonconvective states). The energy conversion was evaluated and fluxes were calculated for the U-, F-, and S-energy. It was found that the energy conversion was greater and the S-energy and F-energy were lower under CP conditions. The convection effect was negative, which means that convection movements were directed vertically upwards. Understanding the membrane transport properties and mechanisms could help to develop and improve the membrane technologies and techniques used in medicine and in water and wastewater treatment processes.
Subject
General Physics and Astronomy
Reference50 articles.
1. Baker, R. (2012). Membrane Technology and Application, John Wiley & Sons.
2. Review of advances in polymeric wound dressing films;Savencu;React. Funct. Polym.,2021
3. Demirel, Y. (2014). Nonequilibrium Thermodynamics: Transport and Rate Processes in Physical, Chemical and Biological Systems, Elsevier.
4. Lipton, B. (2018). The Biology of Belief: Unleashing the Power of Consciousness, Hay House. ISBN-10: 1401923127.
5. Batko, K.M., and Ślęzak, A. (2020). Evaluation of the global S-entropy production in membrane transport of aqueous solutions of hydrochloric acid and ammonia. Entropy, 22.
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献