A High Andean Hydrocolloid Extracted by Microatomization: Preliminary Optimization in Aqueous Stability

Author:

Choque-Quispe Yudith1234ORCID,Choque-Quispe David2345ORCID,Ligarda-Samanez Carlos A.3456ORCID,Solano-Reynoso Aydeé M.7,Froehner Sandro8,Ramos-Pacheco Betsy S.2345ORCID,Carhuarupay-Molleda Yakov Felipe7ORCID,Sumarriva-Bustinza Liliana Asunción9

Affiliation:

1. Department of Environmental Engineering, Universidad Nacional José María Arguedas, Andahuaylas 03701, Peru

2. Water and Food Treatment Materials Research Laboratory, Universidad Nacional José María Arguedas, Andahuaylas 03701, Peru

3. Research Group in the Development of Advanced Materials for Water and Food Treatment, Universidad Nacional José María Arguedas, Andahuaylas 03701, Peru

4. Nutraceuticals and Biopolymers Research Group, Universidad Nacional José María Arguedas, Andahuaylas 03701, Peru

5. Department of Agroindustrial Engineering, Universidad Nacional José María Arguedas, Andahuaylas 03701, Peru

6. Food Nanotechnology Research Laboratory, Universidad Nacional José María Arguedas, Andahuaylas 03701, Peru

7. Department of Basic Sciences, Universidad Nacional José María Arguedas, Andahuaylas 03701, Peru

8. Department of Environmental Engineering, Federal University of Parana, Curitiba 80010, Brazil

9. Academic Department of Chemistry, Faculty of Science, Universidad Nacional de Educación Enrique Guzman y Valle, Lurigancho-Chosica 15472, Peru

Abstract

Aqueous suspensions rely on electrostatic interactions among suspended solids, posing a significant challenge to maintaining stability during storage, particularly in the food and pharmaceutical industries, where synthetic stabilizers are commonly employed. However, there is a growing interest in exploring new materials derived from natural and environmentally friendly sources. This study aimed to optimize the stability parameters of a novel Altoandino Nostoc Sphaericum hydrocolloid (NSH) extracted via micro atomization. Suspensions were prepared by varying the pH, gelatinization temperature and NSH dosage using a 23 factorial arrangement, resulting in eight treatments stored under non-controlled conditions for 20 days. Stability was assessed through turbidity, sedimentation (as sediment transmittance), ζ potential, particle size, color and UV-Vis scanning. Optimization of parameters was conducted using empirical equations, with evaluation based on the correlation coefficient (R2), average relative error (ARE) and X2. The suspensions exhibited high stability throughout the storage period, with optimized control parameters identified at a pH of 4.5, gelatinization temperature of 84.55 °C and NSH dosage of 0.08 g/L. Simulated values included turbidity (99.00%), sedimentation (72.34%), ζ potential (−25.64 mV), particle size (300.00 nm) and color index (−2.00), with simulated results aligning with practical application. These findings suggest the potential use of NSH as a substitute for commercial hydrocolloids, albeit with consideration for color limitations that require further investigation.

Publisher

MDPI AG

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