Experimental Study of Lithium Extraction in the Solid-Liquid Conversion of Low-Grade Solid Potash Ore

Author:

Cui Zihao12,Zhao Yanjun1ORCID,Zhang Yumeng13,Liu Jingjing2,Hu Yufei1,Hu Shengzhong4,Wang Qiang4

Affiliation:

1. MNR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, China

2. Hebei Key Laboratory of Strategic Critical Mineral Resources, College of Earth Sciences, Hebei GEO University, Shijiazhuang 050031, China

3. School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China

4. Qinghai Zhonghang Resources Co., Ltd., Delingha 817000, China

Abstract

There are considerable reserves of low-grade solid potash resources in the shallow part of Mahai Salt Lake in the Qaidam Basin, and the lithium brine resources resulting from solid–liquid conversion and mining are quite abundant. The comprehensive utilization of these resources is an important and urgent problem. In this study, to fully utilize these resources, the shallow low-grade solid potash ore in Mahai Salt Lake was used for systematic simulated ore dissolution experiments, combined with geochemical and X-ray diffraction analyses. The following key results were obtained: (1) Most Li+ in the Mahai mining area was deposited on the soluble salt minerals in silt or clay, and the appropriate concentration of solvent can help to dissolve more Li+ and K+; (2) the saturation time of Li+ was longer than that of K+. Therefore, the dissolution time for the mine can be appropriately extended during the production process to dissolve more Li+; (3) the solid–liquid conversion aqueous solution mining method can separate the lithium part of clay deposits and is associated with salt rock in the brine, which is a potential lithium resource. These experimental results provide a theoretical basis for salt pan production.

Funder

Major Projects of occurrence law of low-grade solid potash in Qarhan salt lake in Qinghai Province and driving dissolution ore Liquefaction technology

State Key Research and Development Project

Publisher

MDPI AG

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